Prof. Harold Wilson Tumwitike Mapoma

Prof. Harold Wilson Tumwitike Mapoma

Author

Physics & Biochemical Sciences

28 publications

Besides teaching and consultancy, Prof. H.W.T. Mapoma has a great passion for research and skills gathering in Environmental Science and Sanitation. He has more than 10 years of teaching experience in environmental pollution and management, water resources management, hydrogeochemical studies, appli...

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Redox control on trace element geochemistry and provenance of groundwater in fractured basement of Blantyre, Malawi

Journal Article
Published 2 years ago, 476 views
Author
Prof. Harold Wilson Tumwitike Mapoma
Co-authors
Xianjun Xie, Liping Zhang, Prof. Harold Wilson Tumwitike Mapoma
Abstract
Assessment of redox state, pH, environmental isotope ratios (δ18O, δ2H) coupled with PHREEQC speciation modeling investigations were conducted to understand trace element geochemical controls in basement complex aquifer in Blantyre, Malawi. Groundwater in the area is typical Ca–Mg–Na–HCO3 type suggesting more of carbonate weathering and significance of carbon dioxide with dissolution of evaporites, silicate weathering and cation exchange being part of the processes contributing to groundwater mineralization. The significance of pH and redox status of groundwater was observed. The groundwater redox state was mostly O2-controlled with few exceptions where mixed (oxic–anoxic) O2–Mn(IV) and O2–Fe(III)/SO4 controlled redox states were modeled. More so, some of the main trace element species modeled with PHREEQC varied with respect to pH. For instance vanadium(III) and vanadium(IV) decreased with increase in field pH contrasting the trend observed for vanadium(V). The isotopic composition of the sampled groundwater varied between −5.89‰ and −3.32‰ for δ18O and −36.98‰ and −20.42‰ for δ2H. The δ2H/δ18O and δ18O/Cl− ratios revealed that groundwater is of meteoric origin through vertical recharge and mixing processes. The d-excess value approximated the y-intercept of GMWL of 10 (d-excess = 9.269, SD = 1.240) implying that influence of secondary evaporative processes on isotopic signature of the study area is minimal. Thus, there is evidence to suggest that groundwater chemistry in the studied aquifer is influenced by inherent processes with contribution from human activities and furthermore, the water originates from rainwater recharge. With such results, more studies are recommended to further constrain the
Year of Publication
2014
Journal Name
Journal of African Earth Sciences
Volume
100
Issue
2014
Page Numbers
335 - 345
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